You have the format wrong. You need to pass the API Key as a header, eg. curl -H "X-MBX-APIKEY: [API_KEY]..... and the signature is not simply your secret_key, there are more steps than that. It involves signing the complete queryString/request body with your secret_key. The process is outlined in the documentation link below.
Refer to this section of the Documentation and make sure to read and understand it thoroughly: Binance API Documentation